Optical properties and emission cross-section of neodymium nanoparticles doped tellurite glass coated with graphene oxide/reduced graphene oxide

التفاصيل البيبلوغرافية
المؤلف الرئيسي:	Hafizah Rajaa Shaari
التنسيق:	أطروحة
اللغة:	الإنجليزية
منشور في:	2024
الموضوعات:	QH Natural history
الوصول للمادة أونلاين:	https://ir.upsi.edu.my/detailsg.php?det=12116
Abstract	Abstract here

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author	Hafizah Rajaa Shaari
author_facet	Hafizah Rajaa Shaari
author_sort	Hafizah Rajaa Shaari
description
format	Thesis
id	upsi-12116
institution	Universiti Pendidikan Sultan Idris
language	English
publishDate	2024
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spelling	upsi-121162025-04-17 Optical properties and emission cross-section of neodymium nanoparticles doped tellurite glass coated with graphene oxide/reduced graphene oxide 2024 Hafizah Rajaa Shaari QH Natural history <p>This study investigated the optical properties of neodymium nanoparticles (NPs) doped</p><p>tellurite glass coated with graphene oxide (GO)/ reduced graphene oxide (rGO). Two series</p><p>of glasses were prepared and coated using melt-quenching and spray-coating methods. The</p><p>X-ray diffractograms proved the amorphous structure of the glass series. The presence of</p><p>non-bridging oxygens in the glass network were proven via FTIR analysis. Meanwhile, the</p><p>existence of neodymium nanoparticles in the tellurite glass network were confirmed using</p><p>TEM analysis. FESEM and EDX analysis showed the morphologies of GO and rGO on</p><p>the glass surface and their chemical elements, respectively. From UV-Vis spectroscopy</p><p>analysis, the optical band gaps of ZBTNd (NPs)-GO and ZBTNd (NPs)-rGO were found</p><p>in the range 2.355-2.998 eV and 2.770-3.125 eV, respectively. Meanwhile, the refractive</p><p>index of ZBTNd (NPs)-GO and ZBTNd (NPs)-rGO were 2.041-2.194 and 2.339-2.657,</p><p>respectively. Furthermore, the oxide ion polarizability (_o2-) of ZBTNd (NPs)-GO and</p><p>ZBTNd (NPs)-rGO were 3.453-3.854 A and 3.360-3.664 A, respectively. The optical</p><p>basicity (_) values for ZBTNd (NPs)-GO and ZBTNd (NPs)-rGO were 1.220 to 1.262 and</p><p>1.174 to 1.214, respectively. The metallization criteria (M) for both glass series</p><p>demonstrate that the glass system has acceptable optical nonlinearity in the range of 0.3 <</p><p>M < 0.4. The nephelauxetic ratio (_) and bonding parameter (_) indicate the covalency</p><p>nature in both glass series. The emission cross-section spectra and gains of the neodymium</p><p>ions (Nd3+) at the transitions of 4F3/2 _ 4I15/2 and 4F3/2 _ 4I13/2 were examined using the</p><p>McCumber theory. All glass series indicate a positive increase of more than 60% in</p><p>population inversion. In conclusion, the coating of GO and rGO on the tellurite glass</p><p>surface gives significant effects on the overall optical properties. Implication of this study</p><p>is it can offer new advancements in the glass coating field for laser glass.</p> 2024 thesis https://ir.upsi.edu.my/detailsg.php?det=12116 https://ir.upsi.edu.my/detailsg.php?det=12116 text eng N/A openAccess Doctoral Perpustakaan Tuanku Bainun Fakulti Sains dan Matematik <p>Abdel-Baki, M., & El-Diasty, F. (2006). Optical properties of oxide glasses containing transition metals: case of titanium-and chromium-containing glasses. 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spellingShingle	QH Natural history Hafizah Rajaa Shaari Optical properties and emission cross-section of neodymium nanoparticles doped tellurite glass coated with graphene oxide/reduced graphene oxide
thesis_level	PhD
title	Optical properties and emission cross-section of neodymium nanoparticles doped tellurite glass coated with graphene oxide/reduced graphene oxide
title_full	Optical properties and emission cross-section of neodymium nanoparticles doped tellurite glass coated with graphene oxide/reduced graphene oxide
title_fullStr	Optical properties and emission cross-section of neodymium nanoparticles doped tellurite glass coated with graphene oxide/reduced graphene oxide
title_full_unstemmed	Optical properties and emission cross-section of neodymium nanoparticles doped tellurite glass coated with graphene oxide/reduced graphene oxide
title_short	Optical properties and emission cross-section of neodymium nanoparticles doped tellurite glass coated with graphene oxide/reduced graphene oxide
title_sort	optical properties and emission cross section of neodymium nanoparticles doped tellurite glass coated with graphene oxide reduced graphene oxide
topic	QH Natural history
url	https://ir.upsi.edu.my/detailsg.php?det=12116
work_keys_str_mv	AT hafizahrajaashaari opticalpropertiesandemissioncrosssectionofneodymiumnanoparticlesdopedtelluriteglasscoatedwithgrapheneoxidereducedgrapheneoxide

Optical properties and emission cross-section of neodymium nanoparticles doped tellurite glass coated with graphene oxide/reduced graphene oxide

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