Synthesis, Characterization And Anticancer Studies Of Ne\V Silver(I)-Nheterocyclic Carbene Complexes Derived From Nitrile-Functionalized Imidazolium Salts
Five new nitrile-functionalized N-heterocyclic carbene (NHC) salts namely, 3-(2-cyanobenzyl)-I-methylimidazolium hexafluorophosphate (1.PF6), 3-(3- cyanobenzy1)-l-methylimidazolium hexafl uorophosphate 1,3-bis(2- cyanobenzyl)imidazolium bromide (3.Br), 1,3-bis(2-cyanobenzyl)imidazolium hexafluor...
| 第一著者: | |
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| フォーマット: | 学位論文 |
| 言語: | 英語 |
| 出版事項: |
2014
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| 主題: | |
| オンライン･アクセス: | http://eprints.usm.my/60836/ |
| Abstract | Abstract here |
| _version_ | 1854969540864114688 |
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| author | Hafiz, Zetty Zuliklia |
| author_facet | Hafiz, Zetty Zuliklia |
| author_sort | Hafiz, Zetty Zuliklia |
| description | Five new nitrile-functionalized N-heterocyclic carbene (NHC) salts namely,
3-(2-cyanobenzyl)-I-methylimidazolium hexafluorophosphate (1.PF6), 3-(3-
cyanobenzy1)-l-methylimidazolium hexafl uorophosphate 1,3-bis(2-
cyanobenzyl)imidazolium bromide (3.Br), 1,3-bis(2-cyanobenzyl)imidazolium
hexafluorophosphate (4.PF6) and 1,3-bis(3-cyanobenzyl)imidazolium
hexafluorophosphate (5.PF6) have been successfully synthesized in excellent yield
(76-91 %). These imidazolium salts then were treated with a basic metal source,
silver oxide, via a simple complexation reaction to afford six novel silver complexes
(C1-C6) in good yields (69-84%). |
| first_indexed | 2025-10-17T08:50:08Z |
| format | Thesis |
| id | usm-60836 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2025-10-17T08:50:08Z |
| publishDate | 2014 |
| record_format | eprints |
| record_pdf | Abstract |
| spelling | usm-608362024-07-16T01:11:15Z http://eprints.usm.my/60836/ Synthesis, Characterization And Anticancer Studies Of Ne\V Silver(I)-Nheterocyclic Carbene Complexes Derived From Nitrile-Functionalized Imidazolium Salts Hafiz, Zetty Zuliklia TP1-1185 Chemical technology Five new nitrile-functionalized N-heterocyclic carbene (NHC) salts namely, 3-(2-cyanobenzyl)-I-methylimidazolium hexafluorophosphate (1.PF6), 3-(3- cyanobenzy1)-l-methylimidazolium hexafl uorophosphate 1,3-bis(2- cyanobenzyl)imidazolium bromide (3.Br), 1,3-bis(2-cyanobenzyl)imidazolium hexafluorophosphate (4.PF6) and 1,3-bis(3-cyanobenzyl)imidazolium hexafluorophosphate (5.PF6) have been successfully synthesized in excellent yield (76-91 %). These imidazolium salts then were treated with a basic metal source, silver oxide, via a simple complexation reaction to afford six novel silver complexes (C1-C6) in good yields (69-84%). 2014-03 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/60836/1/24%20Pages%20from%2000001779818.pdf Hafiz, Zetty Zuliklia (2014) Synthesis, Characterization And Anticancer Studies Of Ne\V Silver(I)-Nheterocyclic Carbene Complexes Derived From Nitrile-Functionalized Imidazolium Salts. Masters thesis, Perpustakaan Hamzah Sendut. |
| spellingShingle | TP1-1185 Chemical technology Hafiz, Zetty Zuliklia Synthesis, Characterization And Anticancer Studies Of Ne\V Silver(I)-Nheterocyclic Carbene Complexes Derived From Nitrile-Functionalized Imidazolium Salts |
| title | Synthesis, Characterization And Anticancer Studies Of Ne\V Silver(I)-Nheterocyclic Carbene Complexes Derived From Nitrile-Functionalized Imidazolium Salts |
| title_full | Synthesis, Characterization And Anticancer Studies Of Ne\V Silver(I)-Nheterocyclic Carbene Complexes Derived From Nitrile-Functionalized Imidazolium Salts |
| title_fullStr | Synthesis, Characterization And Anticancer Studies Of Ne\V Silver(I)-Nheterocyclic Carbene Complexes Derived From Nitrile-Functionalized Imidazolium Salts |
| title_full_unstemmed | Synthesis, Characterization And Anticancer Studies Of Ne\V Silver(I)-Nheterocyclic Carbene Complexes Derived From Nitrile-Functionalized Imidazolium Salts |
| title_short | Synthesis, Characterization And Anticancer Studies Of Ne\V Silver(I)-Nheterocyclic Carbene Complexes Derived From Nitrile-Functionalized Imidazolium Salts |
| title_sort | synthesis characterization and anticancer studies of ne v silver i nheterocyclic carbene complexes derived from nitrile functionalized imidazolium salts |
| topic | TP1-1185 Chemical technology |
| url | http://eprints.usm.my/60836/ |
| work_keys_str_mv | AT hafizzettyzuliklia synthesischaracterizationandanticancerstudiesofnevsilverinheterocycliccarbenecomplexesderivedfromnitrilefunctionalizedimidazoliumsalts |